间位芳纶纤维悬浮液的屈服特性及其与成纸匀度关系的研究
Study on Yielding Properties of Meta-Aramid Fiber Suspensions and Its Relationship with Paper Sheet Formation
收稿日期:2019-09-25  修订日期:2019-10-22
DOI:
关键词:  间位芳纶  压缩屈服应力  剪切屈服应力  成纸匀度
Key Words:meta-aramid fiber  compressive yield stress  shear yield stress  sheet formation
基金项目:
作者单位邮编
王珮瑶 陕西科技大学 710021
张美云 陕西科技大学 
沙九龙* 广西大学 530004
宋顺喜 陕西科技大学 
甄晓丽 陕西科技大学 
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摘要:间位芳纶短切纤维因表面亲水性差,纤维长,在悬浮液中易缠绕絮聚,严重影响成纸的匀度,限制了芳纶纸基材料在国防、电力、交通等高精端领域的应用。为探究间位芳纶悬浮液的絮凝特性,本文从流变学角度,研究了间位芳纶短切与沉析纤维共混悬浮液的絮凝浓度、剪切和压缩屈服应力,同时通过湿法成形工艺探索芳纶悬浮液的屈服流变特性与成纸匀度间的构效关系。结果表明,共混间位芳纶悬浮液的凝结点在0.37~0.64g/L之间,悬浮液的压缩和剪切屈服应力与纤维浓度间分别呈线性和指数函数关系;除纯短切纤维悬浮液外,在同一浓度下,共混间位芳纶悬浮液的压缩屈服应力和剪切屈服应力均随着沉析纤维占比的增大而减小;间位芳纶纤维悬浮液Froude数随着浓度的增大而减小,对特定配比的间位芳纶悬浮液,芳纶纸的匀度指数随着悬浮液Froude数的增大而增大。
Abstract:Due to its poor surface hydrophilicity, meta-aramid staple fibers are easily entangled to form flocs, which seriously affects the uniformity of meta-aramid paper and limits the application of meta-aramid paper based materials in relevant high-end fields such as defense, power and transportation. To investigate the flocculation mechanism of meta-aramid fiber suspensions, the critical flocculant concentration, shear and compressive yield stress of the mixture suspensions of meta-aramid staple fibers and fibrids were examined, and relations between the formation index and rheological properties could be found, based on the rheological theory. The results showed that the gel concentration ranged from 0.37 to 0.64 g/L, and the compressive yield stress and shear yield stress of the suspension were found to depend on the mass concentration via a linear and a power-law relationship, respectively. In addition, both the compressive yield stress and the shear yield stress decreased as the proportion of fibrid increased at a certain concentration, with the exception of pure staple fiber suspensions. Moreover, as the concentration increased, the Froude number were found to decrease accordingly, and the formation index of aramid paper with a fixed staple fiber to fibrid ratio increased with increasing the Froude number.
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