AS-AQ法制备高聚合度三桠皮纸浆的蒸煮工艺研究
Research on the Pulping Process for Preparing Edgeworthia chrysantha Pulp with High Degree of Polymerization by AS - AQ Method
投稿时间:2025-02-18  修订日期:2025-03-26
DOI:
关键词:  三桠皮  AS-AQ法  聚合度  蒸煮
Key Words:Edgeworthia chrysantha  AS - AQ  Degree of polymerization  Pulping
基金项目:国家科技基础资源调查专项
作者单位邮编
景少云 华南理工大学轻工科学与工程学院 510640
刘梦茹* 华南理工大学轻工科学与工程学院 510640
李海龙 华南理工大学轻工科学与工程学院 
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摘要:本研究以三桠皮为原料制备高聚合度纸浆,比较了烧碱法(NaOH)、烧碱-蒽醌法(NaOH-AQ)、硫酸盐法(KP)以及碱性亚钠-蒽醌法(AS-AQ)四种方法制得浆料的纸浆性能,结果表明采用AS-AQ法蒸煮时三桠皮纸浆聚合度最高,且纸浆得率及白度较高,纤维长宽比大。采用响应面分析实验优化出高聚合度三桠皮纸浆较适宜的工艺条件为:用碱量13.9%,亚硫酸化度54.7%,最高温度137℃,保温时间2.5 h,液比1:6;该条件下制得的三桠皮纸浆聚合度为1942,R16得率为35.04%,纤维长宽比为189,抄造出纸张的白度为63.08%ISO,抗张、耐破和撕裂指数分别为41.99 N·m/g、2.55 kPa·m2/g和22.03 mN·m2/g。可见,AS-AQ法蒸煮能够在保证纸浆得率的同时有效提高聚合度,为高附加值纸浆产品的开发提供了技术依据。
Abstract:In this study, using Edgeworthia chrysantha as the raw material to prepare pulp with a high degree of polymerization, four differernt cooking methods were compared, including caustic soda method (NaOH), caustic soda-anthraquinone method (NaOH-AQ), kraft method (KP) and alkaline sodium sulfite-anthraquinone method (AS-AQ). The results showed that the degree of polymerization of Edgeworthia chrysantha pulp after AS-AQ cooking was the highest, and the pulp yield and whiteness were relatively high, with a large fiber length-to-width ratio. By the means of response surface analysis experiments, more suitable process conditions for preparing Edgeworthia chrysantha pulp with a high degree of polymerization were optimized as follows: the alkali dosage of 13.9%, the degree of sulfitation of 54.7%, the maximum temperature of 137°C, the holding time of 2.5 h and the liquid-to-solid ratio of 1:6. Under these conditions, the yield of R16 of Edgeworthia chrysantha pulp was 35.04%, the degree of polymerization reach up to 1942, the fiber length-to-width ratio was 189 and the whiteness of the paper was 63.08%ISO. Then the tensile index, burst index, and tear index were 41.99 N·m/g, 2.55 kPa·m2/g, and 22.03 mN·m2/g, respectively. Thus it can be seen that AS-AQ cooking here can effectively increase the degree of polymerization while ensuring the pulp yield, providing a technical basis for the development of pulp products with high added value.
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